langchain: fix pinecone upsert when async_req is set to False (#19793)

Issue: 
When async_req is the default value True, pinecone client return the
multiprocessing AsyncResult object.
When async_req is set to False, pinecone client return the result
directly. `[{'upserted_count': 1}]` . Calling get() method will throw an
error in this case.

libs/partners/pinecone/langchain_pinecone/vectorstores.py

@@ -166,6 +166,7 @@ class PineconeVectorStore(VectorStore):
                     batch_size, zip(chunk_ids, embeddings, chunk_metadatas)
                 )
             ]
+            if async_req:
                 [res.get() for res in async_res]
 
         return ids